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101.
We introduce and formalise a scheduling problem that consists in determining an optimum policy (i.e. one that minimises total inventory holding costs) to produce n part-types using a system that is able to share its capacity at all times among these part-types and that switches between an active and an inactive state for pre-known periods of time. Consequently, when active the system must produce enough reserves to meet the demand during the inactive interval. We show that there is always a simple optimum policy in which the production of the part-types is prioritised and, provided the units are properly defined, the optimum priority ordering corresponds to a non-decreasing sequence of the unit holding costs of the part-types. 相似文献
102.
Lucas Montero De Espinosa Juan C. Ronda Marina Galià Virginia Cádiz Michael A.R. Meier 《Journal of polymer science. Part A, Polymer chemistry》2009,47(21):5760-5771
The acyclic diene metathesis (ADMET) polymerization of a phosphorus‐containing α,ω‐diene prepared from a plant oil derived building block is reported. Different ruthenium based metathesis catalysts and conditions were tested to optimize the ADMET polymerization of this monomer. Undecylenyl undecenoate was used as fully renewable comonomer to obtain polyesters with different phosphorus contents and to increase the renewable content of the final polymers. Copolymerization caused marked variations in the molecular weights leading to polyesters from 6 to 38 KDa. The effect of the ADMET polymerization temperature in the thermal properties of the copolymers was studied and their thermal degradation and flame retardant properties were evaluated. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5760–5771, 2009 相似文献
103.
Piotr Dobrzynski Daniele Fabbri Cristian Torri Janusz Kasperczyk Bozena Kaczmarczyk Malgorzata Pastusiak 《Journal of polymer science. Part A, Polymer chemistry》2009,47(1):247-257
A hydroxylactone ((1R,5S)‐1‐hydroxy‐3,6‐dioxabicyclo [3.2.1] octan‐2‐one, abbreviated as LAC) obtained from catalytic pyrolysis of cellulose was investigated as a monomer in the synthesis of polyesters by ring‐opening polymerization (ROP) with L ‐lactide. Although stannous octoate resulted inactive, ROP initiated by zirconium (IV) acetylacetonate afforded novel copolyesters from LAC and lactide mixtures in the bulk at 110 °C. Copolymers were obtained with different LAC content (from 19 to 45%) with a random microstructure as established by detailed NMR analysis. FTIR spectrometry confirmed the presence in the polymer chain of the OH groups originally present in LAC, which do not react during polymerization due to steric hindrance and inter/intramolecular hydrogen bonding. Reaction with trichloroacetylisocyanide proved that OH groups of the polyesters can be readily derivatized. The application of LAC as a comonomer enables the insertion of the alcohol functionality in polylactide avoiding protection/deprotection steps and potentially expanding the realm of biomaterials affordable from carbohydrate feedstock. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 247–257, 2009 相似文献
104.
军事人力资源管理是我军政治工作的重要组成部分。在给出军事人员价值评价指标体系的基础上,对军事人员价值贡献度进行了研究。运用动态规划模型对一定条件下基层部队人力资源按照级别层次进行分配,力求综合价值贡献度最高,人力成本最少,实现与部队级别层次结构的结合,从整体上提高基层部队人力资源的优化配置。 相似文献
105.
提高数据的完备与真实性是水资源监控能力建设的关键。针对国家水资源监控能力建设项目实施以来其监测数据呈现出的异常特征,按照“先粗筛后精选”逻辑,并考虑取用水季节性周期波动的特点,提出采用拉依达准则-模态分解-傅里叶残差修正的水监测数据异常值识别方法,并根据粒子群优化最小二乘支持向量机模型实现对异常数据的重构恢复。通过对企业取用水数据的实例分析,结果表明分段式拉依达准则在其监测异常数据的粗筛中具有较好的适用性,利用傅里叶修正集合模态分解的监测数据序列可取得更佳的拟合效果,从而达到异常数据精选的目的;而粒子群优化最小二乘支持向量机模型对异常数据重构恢复的可信度高于普通最小二乘支持向量机及传统曲线拟合数据重构方法,即该类取用水监测异常数据重构方法可有助于进一步推进其监测数据对实际水资源状态的客观反映。 相似文献
106.
Resource availability optimization is studied on a server–client system where different users are partitioned into priority classes. The aim is to provide higher resource availability according to the priority of each class. For this purpose, resource reservation is modeled by a homogeneous continuous time Markov chain (CTMC), but also by a cyclic non-homogeneous Markov chain (CNHMC) as there is a cyclic behavior of the users’ requests for resources. The contribution of the work presented consists in the formulation of a multiobjective optimization problem for both the above cases that aims to determine the optimal resource reservation policy providing higher levels of resource availability for all classes. The optimization problem is solved either with known methods or with a proposed kind of heuristic algorithm. Finally, explicit generalized approximate inverse preconditioning methods are adopted for solving efficiently sparse linear systems that are derived, in order to compute resource availability. 相似文献
107.
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) has attracted the attention of academia and industry because of its biodegradability, biocompatibility, thermoplasticity and plastic-like properties. However, PHBV is unstable above 160 °C during melt processing at a temperature above the melting temperature, which restricts practical applications as a commodity material. It is widely believed that thermal degradation of PHBV occurs almost exclusively via a random chain scission mechanism involving a six-membered ring transition state. Here, 2,2′-bis(2-oxazoline) (BOX) was selected to modify PHBV to control the formation of six-membered ring ester during thermal degradation. The resulting hydroxyl-terminated PHBVs (HT-PHBVs) had improved thermal stability due to a decrease in the negative inductive effect of the neighboring group of methylene groups at the β-position to the ester oxygen, and a decrease in the electron-denoting effect of substituent group of carbon atoms at α-position to the ester oxygen. The optimal reaction temperature and time were determined to be 95 °C and 6 h, respectively. Compared with those of original PHBV, the temperature determined at 5% weight loss (T5%), the initial decomposition temperature (T0), the maximum decomposition temperature (Tmax), the complete decomposition temperature (Tf) of HT-PHBV prepared under the optimal conditions increased by 31, 24, 19 and 19.1 °C, respectively. 相似文献
108.
Piotr Kirszensztejn Robert Przekop Agnieszka Tolińska Ewa Ma?kowska 《Chemical Papers》2009,63(2):226-232
In the, at present, unstable fuel market, much attention is devoted to alternative technologies for fuel production and development
of alternative products of the petrochemical industry. One of the prospective sources of fuel and alternative petrochemical
products is biomass, and the use of oil plants is one of the possibilities. This paper reports on a possible conversion of
rapeseed oil produced in Poland into intermediate hydrocarbon fractions by pyrolysis combined with parallel catalytic conversion.
The products were analysed by gas chromatography coupled with a mass detector. The process was performed in a fixed-bed reactor
and was monitored by FTIR and 1H NMR. Depending on the catalysts applied, the products contained: water, carbon oxides, hydrogen, aliphatic or aromatic hydrocarbons
accompanied by some amount of C2-C5 hydrocarbons formed during the cracking process.
Presented at the 35th International Conference of the Slovak Society of Chemical Engineering, Tatranské Matliare, 26–30 May
2008. 相似文献
109.
110.
依据多媒体教育资源各层次特征及其关系,通过定义资源媒体特征空间,构建了教育资源库层次索引模型,各层次特征间的映射规则将资源的高层语义特征映射到低层媒体特征,达到了扩充描述语义的目的,提高了查全率;结合学科本体,规范了资源标注内容和用户查询条件的描述,减少了人为因素对查询项和索引项匹配相似度计算的影响,提高了查准率. 相似文献